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Figure 12.13 Comparison of the highest-energy valence-band state given by the empirical pseudopotential (EPP) calculation in the previous section with that given by the Kronig-Penney model of a superlattice under the envelope function/effective mass approximations (EF/EMA)

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Fig. 12.13 displays the results of an identical series of calculations for the uppermost (heavy-hole) valence-band state. The effective mass in the AlAs barriers was taken (and fixed) as the bulk value of 0.51 m0 (Adachi [14], p. 254). In this case, however, the hole effective mass in the GaAs well regions was used as a parameter and varied in order to produce the best fit to the empirical pseudopotential (EPP) results. It can be seen that the Kronig-Penney (EF/EMA) results for an effective mass of 0.45m0 fit the pseudopotential data very well at the larger well and barrier widths, but the match is poorer at narrower widths. This is the result found by Long et al. [21], and indeed should be expected, as the envelope-function approximation (see 1) hinges on the point that the wave function can be considered as a product of two components, with one being a rapidly varying Bloch function (which is factorised out) and the second a slowly varying envelope. It stands to reason that when the period of the envelope approaches that of the Bloch function, as happens here in short-period superlattices, the approximation becomes poorer.

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In essence, the result here can be summarized by saying that, the effective mass of a particle in a quantum well is a function of the well width. The fact that a constant effective mass predicts too high a confinement energy allows the further deduction that the effective mass must be increased as the well width decreases in order to produce agreement with the empirical pseudopotential calculations. In conclusion, the microscopic nature of the pseudopotential calculation gives more detail and allows for more complexity in the eigenstates of heterostructures than methods based on the envelope function/effective mass approximation. In particular, use of the constant-effective-mass approximation has been shown to breakdown for short-period superlattices. 12.4 IN-PLANE DISPERSION In addition to computing the dispersion along the line of symmetry, i.e. the growth (z-) axis, the large-basis method, when applied to superlattices as in Section 12.2, can be used to calculate the in-plane (x-y) dispersion. Such knowledge is fundamental for describing the transport properties of electronic devices which exploit in-plane transport for their operation, such as High Electron Mobility Transistors (HEMTs), as well as optical devices which are influenced by the carriers populating the in-plane momentum states, such as intersubband lasers (see Section 9.22).

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