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The fitting of parabolas (the solid curves) to the data points in Fig 1214 thus allows the effective masses to be calculated (as before in 11) Using the potentials of Mader and Zunger [253], this procedure gives the effective mass along any of the (100) directions in the bulk crystal as 0082m0 In contrast to this, the in-plane electron effective mass for the superlattice is 015mo, which is obviously quite different This would seem to be a general result, at least for relatively short period superlattices; note the period for this example is l0A0 = 565 A A priori, it might be expected that as there is no confinement in the x-y plane (ie parallel to the layers), that the dispersion curves would resemble that of the bulk.

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In fact, as there is confinement along the z-direction, which leads to a shift in the band minimum the band structure around the minima is clearly different from that of the bulk The immediate consequence of which is that the effective mass increases 125 INTERFACE COORDINATION In bulk zinc blende material, each anion, eg As in GaAs, is bonded to four Ga cations It has been shown that the atomic pseudopotential of this As is different from the As" (say) in AlAs, which is merely a reflection of the different chemical nature of the bonding between Ga atoms and Al atoms arising from their different electronegativities Although disappointing in that universal atomic potentials cannot be deduced, the calculations thus far have shown how to deal with such a problem Consider now a heterojunction between two compound semiconductors which share a common species, eg.

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GaAs/AlAs, as illustrated in Fig 1215 The As anion at the interface, as indicated, is bonded to two Ga atoms and two Al atoms, and hence they have neither the character of a fully tetrahedrally coordinated As or As" In fact, they have a character which is intermediate between the two, which can be described by the mean: and hence the interface properties can be described better by the mean in the atomic pseudopotentials, ie..

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